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FLAMEEMISSIONSPECTROSCOPY Dr AshwiniWadegaonkar UNIT6: FLAME EMISSIONSPECTROSCOPY Introduction and theory of atomic emission spectroscopy Instrumentation of single beam flame emission spectrophotometer Measurement ofemission of atomic species Interferences in emission spectroscopy Methods of analysis- calibration curve method, Standard addition method and internal standard method Qualitative and Quantitative Applications of FES INTRODUCTION & THEORY Flame emission spectroscopy is so named because of the use of a flame to provide the energy of excitation to atoms introduced into the flame FES technique deals with the examination of the energy emitted from a substance when suitably excited. It is a well known fact that alkali and alkaline earth metals can be detected by flame test. All alkali and alkaline earth metal ions give characteristic colours in a Bunsen flame. The brightness of the flame colour varies with the amount of sodium or other metal introduced. Emission of such particular radiation by sodium or other metal and the correlation of the emission intensity with the concentration of the element form the basis of FES. ItwasformerlyknownasFlamephotometry
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