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picture1_Postulates Of Quantum Mechanics Slideshare 76611 | Quantum Lecture Cml 2


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File: Postulates Of Quantum Mechanics Slideshare 76611 | Quantum Lecture Cml 2
a wave function in quantum mechanics describes the quantum state of an isolated system of one or more particles there is one wave function containing all the information about the ...

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           A wave                 function in 
           quantum mechanics describes    the 
           quantum state of an isolated system 
           of  one  or  more  particles.  There 
           is one wave  function  containing  all 
           the  information  about  the  entire 
           system,   not  a   separate  wave 
           function  for  each  particle  in  the 
           system. 
           Wave equation for the harmonic motion 
                                            2                  2
                                          d (x) 2  (x)
                                               2          
                                            dx              
                                               2     2
                                                 d (x) (x)
                                             4 2    dx2
                                                  
                                               1               p2
                                          E  mv2 V              V
                                               2              2m
                                                             1
                                          p [2mE V]2
                                           h             h
                                               p                   1
                                                    [2mE V]2
                                                2      2
                                              h     d (x) (E  V)(x)
                                             8 2m     dx2
                                                    
              Postulates of Quantum Mechanics
   Postulate 1:
   State and wave functions. Born interpretation
   The state of a quantum mechanical system is completely specified by a wave 
   function  ψ (r,t) that depends on the coordinates of the particles (r) and time t. These 
   functions are called wave functions or state functions.
   For 2 particle system:                                                                                                     
                                                    
                            (x,y,z,x ,y ,z ,t)
                                      1   1  1   2   2   2
   Wave function contains all the information about a system.
                        wave function             classical trajectory
                 (Quantum mechanics)        (Newtonian mechanics)
   Meaning of wave function:
                                               *
                                             d
                                           
                                         2  
                               P(r) = |ψ| = 
   =>  the probability that the particle can be found at a particular point x and a 
   particular time t. (Born’s / Copenhagen interpretation)
         Implications of Born’s Interpretation
   (1) Positivity:
                        P(r) >= 0
   The sign of a wavefunction has no direct physical significance: 
   The positive and negative regions of this wavefunction both 
   correspond to the same probability distribution.
   (2) Normalization:
                       *d 1
                      
                    all _ space
   i.e. the probability of finding the particle in the universe is 1.
    Physically acceptable wave function
   The wave function and its first derivative must 
    be:
  1) Finite. The wave function must be single 
    valued. This means that for any given values 
    of x and t ,  Ψ(x,t) must have a unique value. 
    This is a way of guaranteeing that there is 
    only a single value for the probability of the 
    system being in a given state.  
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...A wave function in quantum mechanics describes the state of an isolated system one or more particles there is containing all information about entire not separate for each particle equation harmonic motion d x dx p e mv v m h postulates postulate and functions born interpretation mechanical completely specified by r t that depends on coordinates time these are called y z contains classical trajectory newtonian meaning probability can be found at particular point s copenhagen implications positivity sign wavefunction has no direct physical significance positive negative regions this both correspond to same distribution normalization space i finding universe physically acceptable its first derivative must finite single valued means any given values have unique value way guaranteeing only being...

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