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Classification of alcohols. All alcohols, а principle, can be divided into two broad categories i.е. aliphatic alcohols and aromatic alcohols. 1. Aliphatic alcohols. Alcohols in which the hydroxyl group is linked an aliphatic carbon chain are called aliphatic alcohols. For example, Methyl alcohol Ethyl alcohol Isopropyl alcohol Methanol Ethanol 2-Propanol 2. Aromatic alcohols. Alcohols in which the hydroxyl group is present in the side chain of an aromatic hydrocarbon are called aromatic For example. phenylmethanol 2-phenylethanol (benzyl alcohol) (-phenylethyl alcohol) Alcohols are further classified as monohydric, dihydric, trihydric and роlyhydric according as their molecules contain one, two, three, or many hydroxyl groups respectively. For ехаmрlе, Ethyl alcohol 1,2-Ethanediol 1,2,3-propanetriol (Monohydric) (Dihydric) (Trihydric) 2. Aromatic alcohols. Alcohols in which the hydroxyl group is present in the side chain of an aromatic hydrocarbon are called aromatic For example. phenylmethanol 2-phenylethanol (benzyl alcohol) (-phenylethyl alcohol) Alcohols are further classified as monohydric, dihydric, trihydric and роlyhydric according as their molecules contain one, two, three, or many hydroxyl groups respectively. For ехаmрlе, Ethyl alcohol 1,2-Ethanediol 1,2,3-propanetriol (Monohydric) (Dihydric) (Trihydric) I. Тhe alkyl alcohol system. In this system of common nomenclature, the name of an alcohol is derived by combining the name of the alkyl group with the word alcohol. The names are mitten as two words. n-butyl alcohol isobutyl alcohol tret-butyl alcohol II. In this common system, the position of an additional substituent is indicated by use of the Greek alphabet rather than by numbers. -chloroethyl alcohol -bromobutyl alcohol Any simple radical that has а common name may be used in the alkyl alcohol system, with one important exception. The grouping С6Н5 - has the special name phenyl, but the compound C6H5OH is phenol, not phenyl alcohol. phenol Substituted phenols are named as derivatives of the parent compound phenol. The reason for this difference is historical and arose from the fact that phenol and its derivatives have many chemical properties that are very different from those of alkyl alcohols. However, phenyl substituted alkyl alcohols are normal alcohols and often have common names. Examples are: phenylmethanol 2-phenylethanol (benzyl alcohol) ( -phenylethyl alcohol
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